| 1 |  José Ángel Gómez Marchante (SPA) | Saunier Duval - Prodir | 20.31.47 |
| 2 | Alejandro Valverde Belmonte (SPA) | Caisse d'Epargne | 0.07 |
| 3 | Antonio Colom Mas (SPA) | Caisse d'Epargne | s.t. |
| 4 |  Patrik Sinkewitz (GER) | T-Mobile Team | 0.19 |
| 5 | Alberto Contador Velasco (SPA) | Astana - Würth Team | 0.20 |
| 6 | Samuel Sanchez Gonzalez (SPA) | Euskaltel - Euskadi | 0.42 |
| 7 | Miguel Angel Martin Perdiguero (SPA) | Phonak Hearing Systems | 0.44 |
| 8 |  Cadel Evans (AUS) | Davimaton - Lotto | 1.11 |
| 9 | Francisco Javier 'Patxi' Vila Errandonea (SPA) | Lampre - Fondital | 1.21 |
| 10 |  José Bento Azevedo Carvalho (POR) | Discovery Channel Pro Cycling Team | 1.24 |
| 11 |  Davide Rebellin (ITA) | Gerolsteiner | 1.34 |
| 12 |  Bernhard Kohl (AUT) | T-Mobile Team | 1.37 |
| 13 | Leonardo Bertagnolli (ITA) | Cofidis | 1.40 |
| 14 |  Evgeni Petrov (RUS) | Lampre - Fondital | 1.41 |
| 15 | Xavier Tondo Volpini (SPA) | Relax - Gam | 2.11 |
| 16 |  Andriy Grivko (UKR) | Team Milram | 2.18 |
| 17 |  Didier Rous (FRA) | Bouygues Télécom | 2.30 |
| 18 |  Janez Brajkovic (SLO) | Discovery Channel Pro Cycling Team | 2.57 |
| 19 | Sylvain Chavanel (FRA) | Cofidis | 3.01 |
| 20 |  Vladimir Miholjevic (CRO) | Liquigas | 3.11 |
| 21 | José Ignacio Gutiérrez Cataluña (SPA) | Phonak Hearing Systems | 3.14 |
| 22 | Daniel Navarro García (SPA) | Astana - Würth Team | 3.16 |
| 23 | Mikel Astarloza Chaurreau (SPA) | AG2R Prévoyance | 3.19 |
| 24 | Ruggero Marzoli (ITA) | Lampre - Fondital | 3.20 |
| 25 | Iban Mayo Díez (SPA) | Euskaltel - Euskadi | 3.42 |
| 26 | Óscar Sevilla Rivera (SPA) | T-Mobile Team | 3.46 |
| 27 | Manuel Beltran Martinez (SPA) | Discovery Channel Pro Cycling Team | 3.54 |
| 28 | Unai Osa Eizaguirre (SPA) | Astana - Würth Team | 4.40 |
| 29 | Egoi Martinez De Esteban (SPA) | Discovery Channel Pro Cycling Team | 4.52 |
| 30 | Alexandre Botcharov (RUS) | Crédit Agricole | 5.13 |
| 31 | Ricardo Serrano Gonzalez (SPA) | Kaiku | 5.29 |
| 32 |  Chris Horner (USA) | Davimaton - Lotto | 6.23 |
| 33 | Sergio Ghisalberti (ITA) | Team Milram | 6.30 |
| 34 | Haimar Zubeldia Aguirre (SPA) | AG2R Prévoyance | 6.41 |
| 35 | Juan Manuel Gárate Cepa (SPA) | Quick Step - Innergetic | 7.10 |
| 36 | Francesco Bellotti (ITA) | Team CSC | 7.20 |
| 37 | Oscar Freire Gomez (SPA) | Rabobank | 7.38 |
| 38 | Cédric Vasseur (FRA) | Quick Step - Innergetic | 8.01 |
| 39 | Jon Bru Pascal (SPA) | Kaiku | 8.25 |
| 40 | Fabian Wegmann (GER) | Gerolsteiner | 8.52 |
| 41 |  Ivan Ramiro Parra Pinto (COL) | Cofidis | 9.10 |
| 42 | Íñigo Chaurreau Bernárdez (SPA) | AG2R Prévoyance | 9.47 |
| 43 | Carlos Sastre Candil (SPA) | Team CSC | 10.59 |
| 44 | Ruben Lobato Elvira (SPA) | Saunier Duval - Prodir | 11.16 |
| 45 |  Bram Tankink (NED) | Quick Step - Innergetic | 11.30 |
| 46 | Constantino Zaballa Gutierrez (SPA) | Caisse d'Epargne | 12.06 |
| 47 | David Etxebarria Alkorta (SPA) | Astana - Würth Team | 12.10 |
| 48 | Manuele Mori (ITA) | Saunier Duval - Prodir | 12.14 |
| 49 | Danilo Di Luca (ITA) | Liquigas | 12.44 |
| 50 | Matthias Kessler (GER) | T-Mobile Team | 13.14 |
Fränk Schleck (LUX)
Charles Wegelius (GBR)
Dmitri Fofonov (KAZ)
