| 1 |  Theo Bos (NED) | Cervélo Testteam | 04:22:53 |
| 2 |  Mark Cavendish (GBR) | Team HTC - Columbia | |
| 3 |  Graeme Allen Brown (AUS) | Rabobank | |
| 4 |  Luis León Sánchez Gil (SPA) | Caisse d'Epargne | |
| 5 |  Davide Appollonio (ITA) | Cervélo Testteam | |
| 6 |  Michal Golas (POL) | Vacansoleil Pro Cycling Team | |
| 7 |  Jorge Martín Montenegro Adaro (ARG) | Andalucía - Cajasur | |
| 8 | Daniel Moreno Fernández (SPA) | Omega Pharma - Lotto | |
| 9 | Ruben Perez Moreno (SPA) | Euskaltel - Euskadi | |
| 10 |  Jan Bakelants (BEL) | Omega Pharma - Lotto | |
| 11 | Rodrigo García Rena (SPA) | Xacobeo - Galicia | |
| 12 | Matteo Carrara (ITA) | Vacansoleil Pro Cycling Team | |
| 13 | Bartlomiej Matysiak (POL) | CCC - Polsat - Polkowice | |
| 14 |  Aleksejs Saramotins (LAT) | Team HTC - Columbia | |
| 15 |  Sergey Lagutin (UZB) | Vacansoleil Pro Cycling Team | |
| 16 |  Mauricio Alberto Ardila Cano (COL) | Rabobank | |
| 17 | Mikel Landa Meana (SPA) | Orbea | |
| 18 | Rob Ruijgh (NED) | Vacansoleil Pro Cycling Team | |
| 19 | Gustavo Dominguez Lemos (SPA) | Xacobeo - Galicia | |
| 20 | Christophe Brandt (BEL) | Omega Pharma - Lotto | |
| 21 | Jurgen Van Goolen (BEL) | Omega Pharma - Lotto | |
| 22 | Manuel Vazquez Hueso (SPA) | Andalucía - Cajasur | |
| 23 | Serafín Martínez Acevedo (SPA) | Xacobeo - Galicia | |
| 24 |  Johannes Fröhlinger (GER) | Team Milram | |
| 25 |  Stefan Denifl (AUT) | Cervélo Testteam | |
| 26 | Jon Izagirre Insausti (SPA) | Orbea | |
| 27 | Ángel Vicioso Arcos (SPA) | Andalucía - Cajasur | |
| 28 | Gustavo Rodriguez Iglesias (SPA) | Xacobeo - Galicia | |
| 29 | Ricardo Garcia Ambroa (SPA) | Orbea | |
| 30 | Christian Knees (GER) | Team Milram | |
| 31 | Jose Ivan Gutierrez Palacios (SPA) | Caisse d'Epargne | |
| 32 | Fabian Wegmann (GER) | Team Milram | 00:08 |
| 33 | Ezequiel Mosquera Miguez (SPA) | Xacobeo - Galicia | |
| 34 | Xavier Tondo Volpini (SPA) | Cervélo Testteam | |
| 35 |  Dmitry Kozontchuk (RUS) | Rabobank | 00:16 |
| 36 | Denis Menchov (RUS) | Rabobank | |
| 37 | Steven Kruijswijk (NED) | Rabobank | |
| 38 | Pieter Weening (NED) | Rabobank | |
| 39 | Inaki Isasi Flores (SPA) | Euskaltel - Euskadi | 00:21 |
| 40 | Francisco Javier Aramendia Llorente (SPA) | Euskaltel - Euskadi | |
| 41 | Jurgen Van Den Broeck (BEL) | Omega Pharma - Lotto | 00:25 |
| 42 | Linus Gerdemann (GER) | Team Milram | 00:27 |
| 43 | Paul Voss (GER) | Team Milram | |
| 44 | Markus Fothen (GER) | Team Milram | 00:33 |
| 45 | Artur Gajek (GER) | Team Milram | |
| 46 | Kamil Zielinski (POL) | CCC - Polsat - Polkowice | 00:36 |
| 47 | Dariusz Batek (POL) | CCC - Polsat - Polkowice | 00:41 |
| 48 | Wout Poels (NED) | Vacansoleil Pro Cycling Team | |
| 49 | Francis De Greef (BEL) | Omega Pharma - Lotto | |
| 50 | Luis Pasamontes Rodriguez (SPA) | Caisse d'Epargne | |
| 51 | José Vicente Toribio Alcolea (SPA) | Andalucía - Cajasur | |
| 52 | Juan Jose Cobo Acebo (SPA) | Caisse d'Epargne | |
| 53 |  Stéphane Rossetto (FRA) | Vacansoleil Pro Cycling Team | |
| 54 |  Thomas Lövkvist (SWE) | Team Ineos | |
| 55 | Delio Fernandez Cruz (SPA) | Xacobeo - Galicia | |
| 56 | Daniel Sesma Sorbet (SPA) | Euskaltel - Euskadi | |
| 57 | Jorge Azanza Soto (SPA) | Euskaltel - Euskadi | |
| 58 | José Vicente Garcia Acosta (SPA) | Caisse d'Epargne | |
| 59 | David Lopez Garcia (SPA) | Caisse d'Epargne | |
| 60 |  Vasil Kiryienka (BLR) | Caisse d'Epargne | |
| 61 | Gonzalo Rabunal Rios (SPA) | Xacobeo - Galicia | |
| 62 | Matthias Russ (GER) | Team Milram | |
| 63 |  Rasmus Poulsen Guldhammer (DEN) | Team HTC - Columbia | |
| 64 | Miguel Minguez Ayala (SPA) | Euskaltel - Euskadi | |
| 65 |  Marcel Wyss (SWI) | Cervélo Testteam | |
| 66 | Maxime Monfort (BEL) | Team HTC - Columbia | |
| 67 | Vladimir Isaychev (RUS) | Xacobeo - Galicia | |
| 68 | Stephen Cummings (GBR) | Team Ineos | |
| 69 | Adrian Honkisz (POL) | CCC - Polsat - Polkowice | |
| 70 | Brice Feillu (FRA) | Vacansoleil Pro Cycling Team | |
| 71 | Juan Manuel Gárate Cepa (SPA) | Rabobank | |
| 72 |  Philip Deignan (IRL) | Cervélo Testteam | |
| 73 | Iñigo Cuesta Lopez De Castro (SPA) | Cervélo Testteam | |
| 74 | Xabier Zabalo Imaz (SPA) | Orbea | 00:51 |
| 75 | Sergio Carrasco Garcia (SPA) | Andalucía - Cajasur | |
| 76 |  Frantisek Rabon (CZE) | Team HTC - Columbia | 01:25 |
| 77 | Juan Javier Estrada Ruiz (SPA) | Andalucía - Cajasur | 01:29 |
| 78 | Igor Antón Hernandez (SPA) | Euskaltel - Euskadi | |
| 79 | Marco Pinotti (ITA) | Team HTC - Columbia | |
| 80 | Patrick Gretsch (GER) | Team HTC - Columbia | |
| 81 | Koldo Fernandez De Larrea (SPA) | Euskaltel - Euskadi | 01:18 |
| 82 |  João Correia (POR) | Cervélo Testteam | 08:34 |
| 83 | Pablo Lechuga Rodriguez (SPA) | Andalucía - Cajasur | |
| 84 | Jaroslaw Rebiewski (POL) | CCC - Polsat - Polkowice | |
| 85 | Stef Clement (NED) | Rabobank | |
| 86 | Tomasz Kiendys (POL) | CCC - Polsat - Polkowice | |
| 87 | Andoni Blazquez Berasarte (SPA) | Orbea | |
| 88 | Tomasz Lisowicz (POL) | CCC - Polsat - Polkowice | |
| 89 | Noel Martín Infante (SPA) | Orbea | |
| 90 | Benat Urain Epelde (SPA) | Orbea | |
